To gain insights into the turnover-limiting step (TLS) and the resting state of the catalyst, the reaction order with respect to each component was determined using the initial-rate method (Figure 3). The rate of the reaction shows first-order dependences on the catalyst and the oxidant (DTBP) but is pseudo-zeroth-order with respect to the lactone substrate (1b).
请教几个问题 什么叫turnover-limiting step 与rate-determining step 的区别？
resting state of the catalyst的意思？
以及first-order 和pseudo-zeroth-order的意思？
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