不用翻译吧 Vanadium oxide dichloride. Dichlorooxovanadium( IV ), 11CI . Oxodichlorovanadium( IV ) Chapman and Hall Number: HMZ46-P CAS Registry Number: 10213-09-9 Molecular Formula: Cl 2 OV Molecular Weight: 137.846 Accurate Mass: 136.876581 Percentage Composition: Cl 51.44%; O 11.61%; V 36.96% General Statement: Octahedral polymer Source/Synthesis: Synth. by reaction of V 2 O 5 + VCl 3 at 600degrees in a sealed tube Use/Importance: Commercially available. Catalyst for isom. and polym. of alkenes. Astringent for antiperspirants Physical Description: Green solid, dec. at 380degrees to form VOCl 3 + VOCl Other Data: Delta H degrees f minus690 kJ mol minus1 , paramagnetic: mu eff = 1.40mu B (296K), 0.95mu B (113K) Hazard and Toxicity: Corrosive RTECS Accession Number: YW1590000 References: Opperman, H. , Z. Anorg. Allg. Chem. , 1967, 351 , 113, (thermodynamics) Brauer, G. , Handbuch Prap. Anorg. Chem. , 3rd edn., Ferdinand Enke Verlag, 1975, 3 , 1416, (synth) Siefert, H.J. et al. , Z. Anorg. Allg. Chem. , 1981, 479 , 32, (cryst struct, magnetism, ir) Ahadian, F. et al. , Proc. IUPAC, I.U.P.A.C., Macromol. Symp., 28th, 1982 , 1982, 256; CA , 99 , 122989u, (catalysis) Lewis, R.J. , Sax's Dangerous Properties of Industrial Materials, 8th edn., Van Nostrand Reinhold , 1992, DFW800
